It happens in Episode 194 of the Naruto Shippuden series.
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Episode 220: Departure
i dont know the number but its called 'Hinata's confession'
number 38
Episode #143-A is the episode where Naruto has a dream about kissing Sakura. Even though he dreams this he ends up kissing Hinanta.
If you mean the song, the title of it is [Lovers], Naruto