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There is actually 2 episodes, the first one is when Zuko finds the necklace and the seond one is when Zuko shows Katara's Neckalace.

Soo The first one is Book 1-Water Episode 6-Imprisoned. At the end is when zuko finds Katara's Necklace the the second one is Book 1- Water, Episode ___ -The Waterbending Scroll.

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