Hiro appears in the Soul Eater in Season 1 Episode 32.
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Episode 1, will soul eater become a death scythe and episode 4, a remedial lesson in the .
episode 157
The episode is 8. When Soul and Maka have to go to Italy to meet Crona.
They play basketball in Episode 25 (I just watched that episode too lol :)
Crona becomes friends with maka in episode 21