Episode 190 in naruto,pre-shippuden,but still in the first naruto series. It's in the filler episodes
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In Naruto Shippuden, Hinata can be seen in episodes 1, 33, 90-112, 122, 165, 169, 175, 176, 219, 220, 232, 236, 271, 279, 306, 311, 321, 330. Additionally she can be found in clips at the end of many episodes.
And Sakura slaps them? xD That's actually Shippuden Movie 3. ^_^
Hinata started liking naruto when he tried to help her when she was attacked by three boys who thought that she thought she was all tough because she has the byakugan. He tried to do the shadow clone but it was messed up (it was white and retarted) they laughed and kicked her. Until somebody she was with in her clan came. She tried to go back to naruto to thank him but that dude said he is dangerous because of the nine-tailed inside him.
Kakashi fights Zabuza in episodes 7-9 and then there's another battle from episodes 12-19. Hope I helped :-P
it's in episode 60 and 69-69