This sounds like a Tom Selleck movie "Quigley Down Under" Sharp shooter with a special rifle who travels to Australia to work for a rancher "Alan Rickman".
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He is told to take of his boots so that the cowboy who will shoot him can wear it later.
Wanted
they are going to watch a movie
Cowboys have guns so they can simply shoot indians in the head. Cowboys nearly wiped indians out.
"Shoot" (1993). Stars Christopher Atkins, Patrick Cherry, Miles O'Keeffe, Dedee Pfeiffer.