Piper discovered her new powers, the Binding, which allow her to imbue the power of crystals within Aerrow.
When she uses this for the first time, she feels something "dark".
Later, when she and Aerrow are training how to use this power, Cyclonis appears inside Piper's mind and tells her this power is evil.
That's the point when that starts to happen: it was like a kind of blocking, which Cyclonis did, so when Piper was using the power, it weakens her a lot, making her get sick.
This power is so dangerous that it can weakens her, like if it was absorbing her soul's energy, to make her become evil.
If Aerrow wasn't there to save her... well, she could now be called "Master Piper".
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No. Aerrow is not in anyway related to the Dark Ace. The only leading reletive in Storm Hawks is that the original sky knight of the Storm Hawks is his dad and all the other (Finn, Piper, Junko, Stalk, Raidarr) are related to the ones how had their positions original. E.G - Piper would be the daughter of the original Navagater. There's been no indication in the show what they are related at all. The only familial relationships shown in the show is that Aerrow and the original Sky Knight of the Storm Hawks are father and son, Ravess and Snipe are brother and sister and the four raptors are brothers.
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Lots of people think that is the case but it has never been confirmed by Nerd Corps or anything and since it looks like there won't be any more new episodes the true answer to the question will likely remain a mystery.
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Lloyd Piper died in 1983.