Pein, Because Pein killed Jiraiya easilly and Jiraiya and Orochimaru are evenly powerful
pain would win because it was hard for naruto to beat pain in 8 tails but easy to beat orochimaru in 4 tails
don't compare them based off how many forms they have fought of the nine tails because if u were watchin pein couldn't handle naruto even in 6 tails the only reason he went that far was because he was gettin angrier as the fight between them progressed actually and this isn't even a match orochimaru would lose to pein even at full strength
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orochimaru beign equal to jiraya but somehow being kill by sasuke and his uchiha blood line is very hard to explain .deidara has an earth release and knows how to counter genjutsu and has a full mastery of exploding clay but orochimaru having kinjustsu and many snake techniques there pretty even in some ways but im sorry to dissapoint you but orochimaru is slightly stronger.
Naruto vs. Haku, Naruto vs. Orochimaru, Naruto vs. Kimimaru, Naruto vs. Sasuke, Naruto vs. Deidara/Sasori, Naruto vs. Orochimaru, Naruto vs. Pain.
The elephant would win.
the lion will win.
the snake will win.
Piccolo can destroy planets, regenerate limbs and move above the speed of invisibility. Naruto is still several levels lower than Z Senshi, even with 9-tails he'd find a great amount of difficulty fighting Master Roshi.