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Naruto Shippuuden does not have "Seasons". It has Sagas (like all Anime series') The Saga in which Naruto defeats Pain is called the "Pain Invasion Arc".
vegeta saga namek saga captin ginyu saga freiza saga ... garlic jr. saga trunks saga android saga imperfect cell saga perfect saga cell games saga great saiyanman saga world tournament saga babidi saga majin buu saga fusion saga kid buu saga ubb saga
Naruto as his best friend and Mitsuki(that brown-headed girl from the sand who seems to always be near Temari during the Kazekage Retrieval Saga and who looks kinda like Sakura.)as his girlfriend.
the android saga
Naruto Shippuden. Episode 60 or 61 :)