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You need to complete Elizabeth/Theo's requests at the Velvet Room until you complete #22 and get the 'Sugar Key' as a reward. Only then can you fuse King Frost, it isn't a special fusion (four-way, five-way, etc) but simply won't appear on the two-way or three-way fusion grid unless you've got that item. Once you do have the item, you can fuse it via the usual methods, ie, fusing the two Emperor persona above it, Raja Naga and Kingu will step the fusion down to King Frost.

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Q: How do you get king frost in persona 3 portable?
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