NO. They do not like each other, in fact they don't really get along. But, it is kind of weird, they spend a large amount of time together, and when Sanji Started flirting with Nami, Zoro started to get pissed.
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Ussop really does love nami. Think of the obvious reason why. He is always around nami when the crew is out, and that should be enough proof.
Another thing is because what ever nami ASKS ussop to do. He does his best to do it. Watch the show and pay a little more attention to it. You'll see ;).
Ussop loves Nami. It is obvious because when the crew is always gone they are always together. It is true because he is nice to her as well. There you go.
As of the latest manga, Roronoa Zoro - Swordsman, Usopp - Sniper, Sanji - Chef, Nami - Navigator, Tony Tony Chopper - Doctor, Frankie - Shipwright, Nico Robin - Archaeologist, Brook - Musician.
Episode 236
episode 128 in the Japanese version. -Nami flashes all the guys includeing Cobra the king of alabaster in the bath with "happiness punch" then charges them all B100,000 for the look. xD http://i38.tinypic.com/mwqqvs.jpg if you want to get technical tho "she" also flashed them all before that. Bon Clay turned into nami on the ship in EP 92 when they were passing in the mist then flashed everyone to show that his power was completely accurate down to the slightest detail. xD http://i36.tinypic.com/dyn0jo.jpg no... i am not an obsessed fan.... not at all.... >.< those are the 2 instances i can remember off the top of my head that nnami flashed Luffy... on the other hand, there were some other instances as well such as in thrillar bark where nami was pinned to the wall and usopp came in and bowed and said thank you. xD no, i am not a fan of the show at all.
I'm presuming your refering to the fight between Luffy and Usopp back on Franky's island WaterSeven/Aqua Lagoona. Well they were fighting over whether they should leave their ship, Merry, behind as it had become broken beyond repair after their visit to the Sky Island. Usopp wants to save and repair the Merry, but Luffy see's sense and knows it's safer to leave the Merry behind. Usopp challenges Luffy to a dwell, which Zoro forsees and prevents the others from getting involved and stopping them. Luffy, enevitably, wins.