He smokes in the manga but he only started smoking after the death of Asuma and keeps on smoking till he kills Hidan in the Nara forest. after that he stops smoking.
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Ino, Shikamaru, Chouji Asuma
no, shikamaru wont end up with temari cause shikamaru will end up with ino
technically Shikamaru didn't defeat Tayuya, Temari did. after Shikamaru and Tayuya fight for awhile Temari came and helped Shikamaru. She performed an animal summoning and defeated Tayuya.
Shikamaru only sees Shiho as a respectable colleague.
on shippuden, shikamaru defeats hidan on episode 87 or around that.