Yes, Zetsu does have arms, he just hasn't had a chance to use them yet becasue there hasn't been an opertunity where he can use them , when we can see.
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Kishimoto Masashi (author) had originally planned for the akatsuki to be a group of monsters and each character represented something (zetsu = Plant) zetsu was one of them. But he changed the idea of the akatsuki, and he like Zetsu so much he decided to keep him.
Zetsu comes in episode 142 naruto shippuden Japanese book!!!(This is the main part)!!!
Zetsu's ring is green, and he wears it on the right little finger.
This happened in Naruto Shippuden Chapter 678, Black Zetsu Betrays Madara.
Zetsu can summon plants and he can defend himself with his outer layer of hard skin planthe also can digthis answer is made by:BREEDING KITTENS OH YAH!!!