Angus Young is the lead guitarist for AC/DC, and only performs vocals sparingly, such as the "Oi!" chant in TNT. AC/DC's singers were/are Bon Scott, until his death, and Brian Johnson after him.
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Ventura Highway
No, he's the lead guitarist. AC/DC has had several lead singers, but you're probably thinking of either Bon Scott (Dirty Deeds, Highway to Hell) or Brian Johnson (Back in Black, You Shook Me All Night Long).
big meme
I saw him sing it live during the Bat Out of Hell II tour here in Indianapolis with Tony Siragusa.
Yes he did, he released it as a 78rpm record.