The only celebrity that come to mind with initial E. R. is Queen Elizabeth I of England -- Elizabeth Regina. I don't know if Queen Elizabeth II has Regina as a name, but I suspect so from the formal name on coins bearing her profile.
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Some celebrites with the initials E.H. are Ethan Hawke, most notable I think. Then there is Ernest Hemingway (if posthumous celebrities count) and Elisabeth Hasselback (from The View). Hope that helps!
Ricky Martin ?
a fictional character with the initials EC is Edward Cullen from the book series Twilight.
ed kranepool ...baseball
Vanessa Ray (Pretty Little Liars)