I don't know all of them. But episode 96 has like ALL Rin, and I don't know which episode it is, but it's called 'Forever with Lord Sessomeraru.' Or the spelling may be wrong.
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She doesn't directly tell them that Inuyasha is her boyfriend but complains about a certain someone (Inuyasha) in their presence. They assume this someone is her boyfriend.
The movies are more of an individual story line on their own rather than an actual part of the anime. They can be fit into the anime, but are more independent than anything else. The first movie fits 4-8 episodes after Inuyasha defeats Ryoukutsei and learns the backlash wave, and the second fits in the middle of Naraku's disappearance after Inuyasha and Shesshomaru kill him, but before the introduction of the band of seven
Chris appears in episode 7 of season 7. Charmed 7x07 "Someone to Witch Over Me"
InuYasha never actually picks. It's a complicated situation. In the end Kikyo dies for good, and does not come back to life. So, he's left with Kagome. In the end, InuYasha and Kagome get married, but who knows what would've happened if Kikyo lived? I think he would've chosen Kagome because their bond was greater than his bond with Kikyo. In the end, he never picks. He is merely left with no choice but to stay with Kagome. Although, he will never forget Kikyo.
It is not a episode but the 1st movie, InuYasha the movie: Affections Touching Across Time. It is where Menomaru, the son of a demon who was enemies with Inu no Taisho (InuYasha's father), puts Kagome under spell to get her to try and kill InuYasha. Hope this helped! =3