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no there was never a copper quarter
no, but there was on the quarter (probably 1812)
The US has never circulated an aluminum coin. 1n 1941 US quarters were 90% silver; the value is based on condition and mint mark. There's more information at the Related Question.
Neither the US nor Canada has ever made aluminum dimes. Please post a new and more specific question with the country/countries you're referring to.
??? I seriously doubt that President (and General) Eisenhower would have ever worn a pig-tailed wig. The person on the quarter since 1932 has been George Washington.