Both because they both have effects that can damage your body or brain
I would disagree with the above statement, Nicotine is no more harmful to your body than Caffeine and both are classed the same in addictiveness. LD50 Nicotine 50mg / Caffeine 192mg.
In any case Nicotine gum is FDA approved as a stop smoking plan and far safer than smoking.
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Tar is a sticky black carcinogenic substance from which roads are made. It causes lung irritation if inhaled, for example by smoking tobacco. Nicotine is a stimuant (drug) which causes the heartbeat to speed up. This is also absorbed by smoking tobacco.
Tar is more dangerous. Nicotine just addicts you to the cigarette, but tar will damage your lungs.