Usually you fire the right barrel first. It's choke is normally a little open giving a wider spread of shot. You fire the second barrel which is normally a tighter choke at a target farther away. This tighter spread will be concentrated but spread because of the long range assuring more pellets hitting the target. Firing the right barrel at a greater range might have the target escape by having the shot pass by without hitting it because the pellets are spread too far apart.
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