There isn't truly a 'perfect' time, but it is always good to use manners. Be sure it isn't too early in the morning (before 10:00 am), nor too late at night (after 9:00 pm). Also, dinner time (5:00-6:30 pm) isn't a good time. But in my opinion its best if you dont have the courage to ask her out in person your not ready to go out with her at all.
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