According to Guinness Book of World Records:
1. Luxembourg
According to Wikipedia:
1. Portugal
2. Luxembourg
References to back the answers:
According to these sites: Based on Wikipedia, Portugal and Luxembourg are the top 2 countries (in that order) for alcohol consumption per capita supposedly based on information from the World Health Organization (WHO). Based on Guinness Book of World records, Luxembourg holds the overall record.
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I'm proud to say that is my own country, the United Kingdom, the average citizen consumes the equivalent of 10 pints of pure alcohol every year.