First off, all Tequilas are Mezcals, but not all Mezcals are Tequilas.
Tequila must be made from at least 51% Blue Agave and must be made in the tequila region of Mexico. Anything less, or outside of the Tequila region is known as a Mezcal.
Mezcals can be made anywhere in the world, and be made from either green or blue agave.
The famous gusano worm is only found in some Mezcals - never tequila. The gusano worm does not eat the blue agave. They only eat green agaves.
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Two different kinds of spirits. Whisk(e)y is made with one or a number of grains and mezcal/tequila are made with agave.
Tequila is distilled from fermented blue agave in the Tequila region of Mexico. Vodka is distilled from grain or potatoes.
There is a distinct difference in flavors, too.