Hooking up generally refers to a no strings one time sex night. Though it can sometimes refer to starting dating. Making out is when you kiss for a long time, usually french kissing.
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Making out typically involves kissing and physical affection, while hooking up can refer to a range of sexual activities beyond just kissing, such as sexual intercourse or oral sex. Making out is generally more focused on kissing and intimacy, while hooking up implies a more casual sexual encounter.