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An exciplex is an excited state whose wavefunction overlaps a neighboring, dissimilar molecule. In contrast to an exciplex, an excimer is an emissive excited state whose wavefunction overlaps two adjacent molecules of like composition.

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Q: What is the difference between excimer and exciplex?
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Exciplex lasers use a combination of a noble gas--argon, krypton, or xenon, with a reactive gas such as fluoride or chloride. Exciplex lasers are sometimes mistakenly referred to as "excimer" lasers, but "excited dimers" are two of the same molecule, rather than an "excited complex" of different molecules.


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exciplex An electronically excited complex of definite stoichiometry, 'non-bonding' in the ground state. For example, a complex formed by the interaction of an excited molecular entity with a ground state counterpart of a different structure. See also excimer. 1994, 66, 1114; see also 1996, 68, 2241 IUPAC Compendium of Chemical Terminology 2nd Edition (1997)


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