Adjacent to merely means "next to one another". Complementary means that each benefits the other, or goes well with the other. Orange and pink can be adjacent to each other, But orange and blue are complementary to each other.
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Adjacent
adjacent angles can be complementary and supplementary you can see a video of khan
The interior angle of a polygon and its adjacent exterior angle can never be complementary.
Yes
Congruent adjacent complementary angles are two angles of 45° that share one side and its vertex.. which means: A 90° angle divided in two halfs of 45°.