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well a shinigami zanpakyo has a spirit within itself and when the shinigami call out to release it they become on and for arrancars its basically a sword that stores some of their powers so when they release it they evolve into a new form and are stronger in power. so with the arrancar its like ichigo putting his mask on but they have it in a katana rather than a mask basically that's what it is
hope this helped :D
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