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What is a reference electrode?

Updated: 9/28/2023
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A reference electrode is maintained at a certain potential, for comparison by other electrodes.

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The reference electrode has a known and stable potential.

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Q: What is a reference electrode?
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Difference between reference electrode and indicator electrode?

Often electrochemical studies are interested in one of the electrodes of the cell only. The second electrode is present to complete the cell. Electrode of interest is named working electrode or the indicator electrode; the second electrode is know as reference electrode or auxiliary electrode (counter electrode).


What type of electrodes are used in potentiometric titration?

Potentiometric titration is a method to detect potential difference between the indicator electrode and reference electrode and thus determine concentration of chemical component, which reacts with reagent added to a solution potentially in equilibrium at the beginning.The popularly used reference electrode is either silver-silver chloride or mercury sulfate electrode, and the indicator electrode is generally made of glass electrode, platinum electrode and silver electrode or ion selective electrode.


Which limb sensor is the reference or ground electrode?

left arm


Describe the construction of calomel electrode?

It consists of tube in the bottom of which is a layer of mercury ,over which is placed a paste of Hg+HgCl2.The remaining portion of cell is filled with a solution of normal or decinormal or saturated solution of KCl. a platinum wire dipping into the mercury layer is used for making electrical contact. the side tube is used for electrode is formulated as;Hg,Hg2Cl2,KCl. the electrode can be coupled with the hydrogen electrode of unknown pH.


What is the basic technique or basic principle of amperometric titration?

The potential applied between the indicator electrode and the reference electrode is kept constant and the current through the electrolyte cell is then measured on addition of each increament oftitrating solution.

Related questions

What is the purpose of the reference electrode?

A reference electrode is an electrode with a well-known electrode potential. Its main function is to serve as a half cell to build an electrochemical cell.


Difference between reference electrode and indicator electrode?

Often electrochemical studies are interested in one of the electrodes of the cell only. The second electrode is present to complete the cell. Electrode of interest is named working electrode or the indicator electrode; the second electrode is know as reference electrode or auxiliary electrode (counter electrode).


What is a secondary reference electrode?

The primary reference electrode is the hydrogen electrode, which is rather fiddly to work with. Secondary references are chosen for their stability and their reliable potentials so others can be calibrated against them.


Which element is the reference element is chemistry?

Carbon is the reference element for the definition of the mole. In electrochemistry, the reference element/electrode is the Hydrogen electrode and all electrode potentials are against the hydrogen standard.


What is electrode potential-?

Electrode potential is the voltage that an electrode is at. This has to be measured versus a reference electrode


Why mercury placed at the bottom of calomel electrode?

because calomel act as a reference electrode


What type of electrodes are used in potentiometric titration?

Potentiometric titration is a method to detect potential difference between the indicator electrode and reference electrode and thus determine concentration of chemical component, which reacts with reagent added to a solution potentially in equilibrium at the beginning.The popularly used reference electrode is either silver-silver chloride or mercury sulfate electrode, and the indicator electrode is generally made of glass electrode, platinum electrode and silver electrode or ion selective electrode.


Where can you buy saturated calomel reference electrode?

(UK) ACM, scimed, Sentek


Which limb sensor is the reference or ground electrode?

left arm


What is difference between standard hydrogen electrode and normal hydrogen electrode?

E(SCE)-E(H)=241 mV @25°C SHE is a primary standard electrode bt SCE is secondary reference electrode use for more easier work than SHE & SCE,s potential also measured by taking SHE as reference electrode.


How do you measure electric potential?

A voltmeter is an instrument used to measure electric potential difference. The voltmeter have two electrodes, reference electrode and test electrode, the electrodes are put in two different places where you want to find the potential difference. For instance, if the test electrode is placed on the positive pole and the reference electrode on the negative pole of a 3V battery, the voltmeter would read '+3 volts'.


What is open circuit potential which is used to determine corrosion of materials?

The open circuit (oc) potential is the potential of the working electrode relative to the reference electrode when no potential or current is being applied to the cell.