The United States used the atomic bomb offensively during WWII. That is pretty close to nuclear weapons.
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The only country that has ever used nuclear weapons in any war was the US, at the end of WW2.
The only country to ever use nuclear weapons in war is the United States with the two bombs they dropped on Japan. No other country has ever actually used a nuclear weapon.
No nuclear weapons were used in the korean war
While many countries have exploded test weapons, only the United States has ever used Nuclear weapons against an adversary. Two bombs were dropped on two cities in Japan Hiroshima and Nagasaki in 1945, to bring WWII to an end.
The U.S used no nuclear weapons whatsoever on Vietnam.