Malted barley is the main ingredient in pretty much all beers, even some gluten free beers use extremely low amounts of refined barley malt extract.
If you want a beer specifically not made with any barley at all, I would recommend reading labels and calling breweries. You'll probably have to avoid all mass market breweries, though I believe AB-InBev does make a sorghum lager named Redbridge (no idea if it's totally barley free).
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