The difference between early tools and modern tools is that early tools were made from stone but modern tools are made from metals.
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It really depends on how you define early and modern man, but generally, early man's tools were made of bone, stone, flint, and eventually bronze. Modern man's tools are made today out of a variety of metals, such as iron and steel (iron containing carbon and other substances).
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The method is the manner in which you use the tools for teaching.
Absolutely! Modern man (Homo Sapiens) have never existed without technology, the ancestors of modern man invented many technologies (e.g. edged stone tools, bone tools, fire making tools) that modern man improved on. Science in the modern sense has only existed for about 400 years. Modern man invented many technologies long before that by trial and error (e.g. metal working, brewing fermented drinks, cheese making, glass making and blowing, even a simple electric battery before 3000 BC).