The correct grammar would be "What a relief."
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"There are some mild analgesics used to relieve pain." "The new lanes should relieve some of the traffic congestion on the bridge." "I went to the bathroom to relieve myself."
In the relief sculptures on the Arch of Titus, figures are carved in high relief with deep undercutting.
To relieve
Put ice on it
A vent is a opening for the relief of gas or liquid pressure.