You can use both who and whom you trust.
Who can be used as a subject and an object of a clause, but not object of a preposition.
Whom can only be used as an object.
She is the one who is always there for me. (not whom because who is the subject of is)
_She is the only one who (_or whom) I trust. (object of trust)
She is the one on whom (not who) I can rely . (object of the preposition on)
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