It differs depending on yourregionalkeyboard.
UK: Hold shift, press the key that has @ (far right,nextto the large enter key)
Canada & US: Hold shift, press the number 2
Dutch: Hold shift, press the key that comes before the number 1
For a specific answers, re-ask giving an exact country.
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The easiest way, is to drag & drop it from the character map... First, open the document you need the @ sign in then...
Click Start. Select All Programs. Select Accessories. Select System tools. Select Character Map. Find the @ symbol on the page and simply drag it onto the document you opened earlier.
The keyboard has a at sign that looks like this, @, all you have to do is press shift and the at sign together and there you have it!
This is extremely simple. Just press the Shift key and 2 together and you will get the symbol '@'
Try it and let us know if you were able to do it.
You make the @ symbol by holding downb the [shift] key (usually the first key in the second row from the bottom) and hitting the [2] key at the same time.