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How can you not? I can think of a dozen ways just off the top of my head:

# Odor # Boiling point # Freezing point # NMR spectrum # Flammability # IR spectrum # Does it dissolve salt # Does it mix with something known to be water # Density # Surface tension # Index of refraction # Does it expand upon freezing

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Q: How can you tell the difference between hexane and water?
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