You should probably know her well which makes it a lot easier. Don't make it too sudden and fast. Make sure she's interested and she is ready. She should be willing and allowing you to do it, otherwise you'll go home with a slap from the girl. Start by dancing with her; slow dancing is a good one. Compliment her and stare at her in the eyes the whole time. Have a conversation. Silence is awkward. Make her feel comfortable when you dance. When you are ready for the kiss, lead her outside where you two can be alone. Compliment her some more. Make her she still feels comfortable and is ready for the kiss. You should NOT make out with her or anything. Most likely she's not ready. Just a light kiss on the lips. And as you reach towards her lips, go slowly. If she liked it, she'll smile. You can get another kiss, by going back inside and dancing with her again. This time, hug her when you dance, which will be romantic and will make her feel good. If she looks into your eyes passionately, she wants another kiss. This time you dont have to kiss her lightly. You can kiss her with more passion. Then walk outside and hold hands. And talk some more. She will go home really liking you and thinking about you the whole time. She might end up as your girlfriend if you keep it up.
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You don't at school because it could get you into trouble. First, you have to make sure she would want you to kiss her. I suggest you get a group of your friends together for a movie and Pizza and include her. This way you can get to know her, talk with her, and later can ask her out. A group date like this takes all the pressure off of a first date and that first kiss.