A first kiss is generally thought of to be your first kiss with genuine emotional involvement. If you gave someone a little peck when you were young, it's not necessarily a big deal or set in stone as the first. A first kiss is that moment where both people are really excited about each other and want to kiss each other for the first time.
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A kiss on the neck would typically not be considered a first kiss, as a first kiss is usually exchanged on the lips. However, everyone's definition of a first kiss may vary, so it ultimately depends on how you personally view and value the experience.
Kinda depending on what kinda kiss you do if it's just a simple peck then no but if it's a French kiss or something then yes