Like girls, guys have their own preferences. I've had boys that like kisses on their necks. One thing that they really seem to like are small nibbles on their neck. Not too hard though. Just try it out and you should be able to tell if he likes it or not. Communication is very important in a relationship though, so you two should be able to talk to one another about anything, including turn-ons.
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Some boys may enjoy kisses on their necks as a form of affection and intimacy, as this area is considered to be sensitive and can be pleasurable for many people. However, preferences for physical affection can vary from person to person, so it's important to communicate and respect boundaries with your partner.