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34-0-0 is straight Ammnium Nitrate fertilizer which comes in many forms from powder to granular.

32-0-0 could be made up of a number of diffrent options, it could be 34-0-0 and filler mixed to reduce the N level, it could also be 46-0-0 (urea) and filler again mixed to bring down the N content. If the 32-0-0 is in liquid form then it is 32% UAN solution (note 32% UAN needs constent mixing to avoid salting out)

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