To delete photos from iPod touch:
In iTunes, select the device icon in the Devices list on the left. Click the Photos tab in the resulting window.
Choose "Sync photos from."
On a Mac, choose iPhoto or Aperture from the pop-up menu.
On a Windows PC, choose Photoshop Album or Photoshop Elements from the pop-up menu.
Choose "Selected albums" and deselect the albums or collections you want to delete.
Click Apply.
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You can delete photos from your ipod by deleting them in iphoto first and then re-connecting your ipod to you computer and resyncing. You will notice the pictures you have deleted will be gone after your ipod is done syncing with your computer.