if you want to use the same account, you have options, you can buy or upload songs to your library and plug one iPod in, sync, then do the came to the other, then you will have the same songs on each. Or you can click on your ipod when it is plugged in and click the box under settings that say, sync only cheaked songs. then you can choose which you want to have. or if you want to have your own library, you can create a new user for that computer and habe your own.
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First make sure you have iTunes.(I presume you do).
1. Set up two playlists in iTunes.
2. Set the iPod preferences in iTunes so that the iPods are manually managed.
3. When you plug in the first iPod, go back into Edit: Preferences: iPod and change the settings there so that it's automatically updating from the first iPods playlist.
Then update. Then set it back to manual management in the iPod preferences in iTunes.
4. For the other iPod, do the same thing except make sure iTunes is updating from the second iPod.
I'm sure you have to update the settings each time you plug in a different iPod.