Oh, dude, technically speaking, you can't smoke a cigarette through your anus because it's not designed for that kind of activity. Your mouth and lungs are the designated smoking areas, so let's stick to the traditional method and leave the backdoor out of it, shall we?
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No, you cannot smoke that way. You cannot take in air through the digestive tract, particularly not in from that end. You can insert a cigarette there, but it is rather pointless and you risk burning yourself.