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The alkali metals are Li,Na,K,Rb,Cs,Fr.If v see their general electronic configuration,v see that its (n-1)p6 ns1.That means the outer most s orbital contains 1 unpaired electron and just in the inner shell there is fully filled p orbital. 1st ionisation energy is the amount of energy required to remove 1st electron from the outermost shell of an isolated gaseous ion.here v see that the energy required 2 remove 1 electron from outermost shell will be very less cos it helps the atom to achieve fully filled stable electronic configuration. On the other hand,2nd ionisation energy is the energy required 2 remove an electron from isolated gaseous +1 atom,means atom from where 1 electron has already been removed. So here,it is very difficult to remove 1 more electron from the stable fully filled p orbital and large amount of energy is needed.Hence the 2nd IE shoots up considerably as compared to d 1st IE. Hope it's clear...:)..

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Minerva Orn

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3y ago

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Think about what happens when you ionize an alkali metal (keeping in mind that alkali metals are the first group and contain 1 valence electron). When you ionize an alkali metal, you remove it's one valence electron. The first ionization energy is relatively low, because this actually stabilizes the atom. However, the second ionization energy is much higher because the already ionized alkali metal now contains a stable outer shell and is much less willing to lose another electron.

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Wiki User

12y ago
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The alkali metals are Li,Na,K,Rb,Cs,Fr.If v see their general electronic configuration,v see that its (n-1)p6 ns1.That means the outer most s orbital contains 1 unpaired electron and just in the inner shell there is fully filled p orbital. 1st ionisation energy is the amount of energy required to remove 1st electron from the outermost shell of an isolated gaseous ion.here v see that the energy required 2 remove 1 electron from outermost shell will be very less cos it helps the atom to achieve fully filled stable electronic configuration. On the other hand,2nd ionisation energy is the energy required 2 remove an electron from isolated gaseous +1 atom,means atom from where 1 electron has already been removed. So here,it is very difficult to remove 1 more electron from the stable fully filled p orbital and large amount of energy is needed.Hence the 2nd IE shoots up considerably as compared to d 1st IE. Hope it's clear...:)..

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Wiki User

16y ago
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The attraction between the electrons involved and the atomic nucleus is stronger.

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Wiki User

7y ago
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Q: Why second ionization energy of alkali metals are higher than first ionization energy?
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