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Cu2I2 is precipitates in light pink colour due to adsorption of I2 and the precipitate releases I2 very slowly. Therefore very small amount of potassium thiocyanate is added towards the end point which helps to displace the adsorbed I2 quickly by combining with Cu2I2 to form CuSCN which has less tendency to adsorb I2.

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13y ago
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6mo ago

Potassium thiocyanate is added to the redox iodometric titration of copper sulfate to react with the excess iodine produced during the reaction. This reaction forms a stable product, potassium iodide, which helps reach the correct endpoint of the titration by preventing the iodine from reacting with other substances. It also helps improve the accuracy and precision of the titration results.

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Q: Why potassium thiocyanate is added in redox iodometric titration of copper sulphate?
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Easy Analytical techniques zinc sulphate Ferrous sulphate Copper sulphate through titration method?

For analysis through titration method: Zinc sulfate can be titrated using EDTA as the titrant. Ferrous sulfate can be titrated using potassium permanganate as the titrant. Copper sulfate can be titrated using sodium thiosulfate as the titrant.


How do you determine the sulphate?

Sulphate ions can be determined using methods such as gravimetric analysis, titration with barium chloride, or ion chromatography. In gravimetric analysis, sulphate ions are precipitated as barium sulphate and weighed. Titration with barium chloride involves adding a known volume of barium chloride solution to the sample containing sulphate ions, and the excess barium chloride is back-titrated with a standard solution of a titrant such as potassium chromate. In ion chromatography, separation and quantification of sulphate ions are done using a chromatographic column with specific properties.


What is the symbol potassium sulphate?

The symbol for potassium sulphate is K2SO4 . It contains K+ and SO42- ions.


Which one is better for titration with Ferrous Ammonium Sulphate potassium dichromate or potassium permaganate and why?

Potassium dichromate is better for titration with ferrous ammonium sulfate because it reacts with ferrous ions in a 1:6 ratio, making it easier to determine the equivalence point accurately. Potassium permanganate, on the other hand, reacts with ferrous ions in a 1:5 ratio, which can lead to less precise results and requires a more careful technique.


Potassium sulphate and potassium sulphate both contain potassium and?

Well, first off, you list the same substance twice but potassium sulfate contains potassium, sulfur, and oxygen.


Why ferrous sulphate is not used in redox titration?

Ferrous sulfate is not used in redox titrations because it is easily oxidized by air in a laboratory setting, leading to inaccurate results. It is also easily hydrolyzed in the presence of water, affecting the stability and reliability of the titration. Alternative titrants with more stable and reliable properties, such as potassium permanganate or potassium dichromate, are preferred for redox titrations.


What is the electrovalency of potassium in potassium sulphate?

The electrovalency of potassium in potassium sulfate is +1. This is because potassium is in Group 1 of the periodic table and typically forms ions with a charge of +1.


What compound is potassium sulphate?

K2SO4


What is Benedict solutions?

Benedict's solution, or Benedict's reagent, is a solution used for the analysis of reducing sugars. It may be qualitative or quantitave. The former is composed of copper sulphate, sodium carbonate and sodium citrate while the later additionally contains potassium ferrocyanide and potassium thiocyanate. The solution is so named after Stanley Rossiter Benedict, the scientist who created it.


What is the formula of potassium sulphate?

Type your answer here.k2so4


What is the chemical formula of potassium sulphate?

K2so4


What is the potassium sulphate chemical formula?

K2so4