Why is polystyrene brittle?

Answer 1

Unfilled polystyrene is also known as crystal polystyrene (PS) or general purpose polystyrene (GPPS). However, since crystal polystyrene is brittle, other polymers are added to polystyrene to improve its strength, and copolymers are formed as a result. One such copolymer is high impact polystyrene (HIPS), which is produced by adding polybutadiene rubber to polystyrene during the polymerization process. HIPS is tougher and has a greater impact strength than unfilled polystyrene.

There are different types of polystyrene. Extruded polystyrene (XPS) is one form of the polymer that has high tensile strength, with good elasticity. It is commonly known as Styrofoam™. The other common form of polystyrene is expanded polystyrene (EPS). Both EPS and XPS are made from similar materials but there are difference between the two. XPS has a higher density as compared to EPS, due to the absence of air passages between its cells. The higher density makes XPS more rigid and strong. Also, XPS is waterproof and is an effective thermal insulator.

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Answer 2

Polystyrene is brittle because its molecular structure consists of long, straight chains of hydrocarbons that are packed closely together. This arrangement makes the material rigid and prone to stress concentration, causing it to break easily under tension or impact.

Answer 3

Yes