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Na plus or Al 3plus, Al 3+ has greater coagulating power

Cl- or SO4^2- , SO4^2- has greater coagulating power.

Look at their net charges

Na+ has one charge

Al3+ has three

so Al3+ has greater coagulating power.

Cl- has one charge

SO4^-2 has two.

so SO4^2- has greater coagulating power

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