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The question is nonsense. WHICH bond angle? There are many of them in a molecule the size of estradiol.
90 degrees is the value of the smallest bond angle in IF4.
The value of the bond angle in XeF2 is 180 degrees.
The bond length is equal to the linear distance between the nuclei of the bonding atoms. The bond angle is equal to the angle between any two consecutive bonds in a molecule or ion. Bond angles of molecules and ions are usually determined by using the VSEPR theory.
The bond angle of IF5 is approximately 90 degrees.