The products becoming more ordered than the reactants
Entropy increases. In a reaction comprised of sub-reactions, some sub-reactions may show a decrease in entropy but the entire reaction will show an increase of entropy. As an example, the formation of sugar molecules by living organisms is a process that shows decrease in entropy at the expense of the loss of entropy by the sun.
The entropy of the universe must increase during a spontaneous reaction or process. This is in accordance with the Second Law of Thermodynamics, which states that the total entropy of an isolated system can never decrease over time.
The favorability or spontaneity of a reaction increases when the overall entropy of the system increases, or when the free energy of the system decreases. This can happen when reactants are in a more disordered state, when the system achieves greater stability, or when the reaction releases heat.
no.
No, the decrease in entropy of water turning into ice does not violate the second law of thermodynamics. The second law states that the total entropy of an isolated system can never decrease, but entropy can decrease locally within the system as long as there is a corresponding increase in entropy elsewhere. In the case of water turning into ice, the decrease in entropy of the water molecules is offset by an increase in entropy in the surroundings.
The products becoming more ordered than the reactants
Entropy increases. In a reaction comprised of sub-reactions, some sub-reactions may show a decrease in entropy but the entire reaction will show an increase of entropy. As an example, the formation of sugar molecules by living organisms is a process that shows decrease in entropy at the expense of the loss of entropy by the sun.
CO(g)+3H2(g)->CH4(g)+H2O(g)
It increases
An exothermic reaction with a negative entropy change indicates that the reaction releases heat to its surroundings and results in a decrease in disorder or randomness of the system.
Complex reactions where small molecules are converted into larger, more ordered structures, such as polymerization or crystallization, can decrease entropy within a cell. These reactions reduce the randomness and disorder of molecules, leading to a more ordered state and a decrease in entropy.
A change in temperature can affect the entropy change (delta S) of the surroundings in a chemical reaction. When the temperature increases, the surroundings absorb more heat energy, leading to an increase in entropy. Conversely, a decrease in temperature results in a decrease in entropy of the surroundings.
The amount of randomness in the system
An endothermic reaction which absorbs heat from the surroundings decreases the entropy of the surroundings. This is because the surroundings lose thermal energy during the reaction, leading to a decrease in the disorder or randomness of the surroundings.
The entropy of the universe must increase during a spontaneous reaction or process. This is in accordance with the Second Law of Thermodynamics, which states that the total entropy of an isolated system can never decrease over time.
First of all, entropy is the defined as the extent to which something is disordered. In chemistry, for entropy in a SYSTEM to decrease, the products of a reaction must be less disordered than the reactants. The extent of "disordered-ness" can be seen by the physical states of the substances. A gas is more disordered than a liquid, which is more disordered than a solid. So, an example of a reaction that leads to a decrease in entropy is: HCl(gas) +NH3(gas) -----> NH4Cl(solid) So you see, there are more gaseous molecules in the reactant side of the equation than in the product side, which means the products are less disordered than the reactants. ----------------------------------------------- However, one must note that if the entropy of a system(reaction) decreases, the entropy of the surroundings should increase. This is because change in TOTAL entropy(A) = change in entropy of SYSTEM(B) + change in entropy of SURROUNDINGS(C). It is a rule that A must increase in every case ( have a positive value). If the B is negative(a decrease in entropy), C must be positive(an increase in entropy) to keep the value of A positive.
2NO2(g) N2O4(g)