Yes. German engineers Ernst Ruska and Max Knoll built the first machine in 1931 in Germany. It didn't outperform the best optical microscopes, but it served to demonstrate the ideas. A couple of years later, Ernst Ruska (working for Siemens in one of their German locations) built an electron microscope that surpassed the resolution limits of an optical microscope. Wikipedia has a nice article on the history of the electron microscope, and a link is provided to that post. You'll find it below.
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The electron microscope was invented by Max Knoll and Ernst Ruska in Germany in 1931. Ruska was awarded the Nobel Prize in Physics in 1986 for his contribution to the development of electron microscopy.
scanning electron microscope
The light microscope came first, dating back to the 17th century. The electron microscope was developed in the 20th century, with the first electron microscope built in the 1930s.
An electron microscope is capable of magnifying objects up to a million times. This type of microscope uses a beam of accelerated electrons to view specimens at a much higher resolution compared to light microscopes.
The transmission electron microscope was invented by German physicist Ernst Ruska in 1931, along with his collaborator Max Knoll. Their invention revolutionized the field of microscopy by allowing scientists to observe structures at the nanoscale level.