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First, cyclohexatriene is NOT A REAL MOLECULE because it is unstable with respect to the formation of benzene.

If it were to exist, cyclohexatriene would be a six-membered non-aromatic hydrocarbon with alternating double (short) and single (long) bonds (point group D3h) while benzene is a six-membered aromatic hydrocarbon with equivalent bonds (point group D6h). This is confusing because many chemists draw benzene with alternating double and single bonds even though all its bonds are equivalent.

Thus, cyclohexatriene is a strictly theoretical molecule but one that is quite useful for demonstrating the concept of resonance stablilization.

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15y ago
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5mo ago

One way to distinguish between benzene and cyclohexene is through a bromine water test. Cyclohexene will react with bromine water, turning it from orange/red to colorless due to the addition reaction with the double bond in cyclohexene. Benzene, being a stable aromatic compound, will not react with bromine water and the orange/red color will remain.

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12y ago

perform gattermann kochs reaction on benzene. you will get an aldehyde. on the obtained aldehyde use tollens reagent. you will get a silvery white ppt.

on performing gatterman kochs reaction on cyclohexane , this will yield no reaction.

hence this is how you differentiate between benzene and cyclohexane

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12y ago

Benzene and cyclohexane have the same number of carbon atoms (6). The main difference between the two molecules is the number of hydrogen atoms and bonding.

In benzene 6 carbon atoms form a ring with alternating single and double bonds (the bond structure is actually a resonance hybrid, but that is probably outside the scope of your class). Each carbon also has a single hydrogen atom bonded to it:

H

|

H C H

\ / \\ /

C C

|

C C

/ \ // \

H C H

|

H

Cyclohexane is much the same except it contains 2 H atoms per C and only single bonds:

H H

\ /

H C H

\ / \ /

H-C C-H

| |

H-C C-H

/ \ / \

H C H

/ \

H H

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14y ago

put them in separate test tubes with some dilute solution of potassium permanganate.....

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12y ago

one is spelt with a Y

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13y ago

Cyclohexane is C6H12 and benzene is C6H6.

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Q: Test to distinguish between benzene and cyclohexene?
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