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An isothermal calorimeter is a tool used to bind small molecules to larger macromolecules, and determine the thermodynamic parameters of interactions in a solution. An isoperibol calorimeter measures the heat created by a sample burned under an oxygen atmosphere in a closed vessel surrounded by water, in controlled conditions. The measurement is known as a BTU value.

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βˆ™ 10y ago
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βˆ™ 9mo ago

In an isothermal calorimeter, the temperature inside the calorimeter remains constant during the measurement, preventing any heat exchange with the surroundings. In an isoperibol calorimeter, the calorimeter is well-insulated and allows heat exchange with the surroundings, but the heat loss or gain is accurately measured and compensated for.

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βˆ™ 11y ago

An isoperibolic calorimeter has a constant temperature of the reactor jacket.

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Q: Difference between isothermal and isoperibol calorimeter?
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What are the key differences between an adiabatic and isothermal graph in thermodynamics?

In thermodynamics, the key difference between an adiabatic and isothermal graph is how heat is transferred. In an adiabatic process, there is no heat exchange with the surroundings, while in an isothermal process, the temperature remains constant throughout the process.


What is the relationship between enthalpy and temperature in an isothermal process?

In an isothermal process, the temperature remains constant. Therefore, the enthalpy change is directly proportional to the temperature change.


What is the difference between a compressible fluid and an incompressible fluid?

The density of a compressible fluid changes with pressure, while the density of an incompressible fluid is not affected by pressure (assuming isothermal conditions).


What does the PV diagram of an isothermal expansion illustrate?

The PV diagram of an isothermal expansion illustrates the relationship between pressure and volume during a process where the temperature remains constant.


What is the relationship between enthalpy and the isothermal expansion process?

In an isothermal expansion process, the enthalpy remains constant. This means that the heat energy exchanged during the expansion is equal to the work done by the system.


How can one propose a method to determine the heat capacity of the calorimeter?

To propose a method to determine the heat capacity of a calorimeter, one can conduct an experiment where a known amount of heat is added to the calorimeter and the resulting temperature change is measured. By using the equation Q mcT, where Q is the heat added, m is the mass of the calorimeter, c is the specific heat capacity of the calorimeter, and T is the temperature change, the heat capacity of the calorimeter can be calculated. This method allows for the determination of the heat capacity of the calorimeter by analyzing the relationship between the heat added and the resulting temperature change.


What are the use of a calorimeter?

A calorimeter is used to measure the heat released or absorbed in a chemical reaction. It is also used to determine the heat capacity of a substance and to calculate the energy content of food by burning it in oxygen.


Difference between isothermal and isobaric heating of saturated steam?

Isothermal heating of saturated steam occurs at constant temperature, while isobaric heating occurs at constant pressure. During isothermal heating, the temperature of the steam remains constant as it absorbs heat energy and undergoes a phase change. In contrast, during isobaric heating, the pressure remains constant as the steam absorbs heat energy, leading to an increase in temperature while remaining in the vapor state.


What error is introduced by including only the water in the calorimeter as the surroundings?

By considering only the water in the calorimeter as the surroundings, the error introduced is neglecting the heat exchange between the water and the actual surroundings outside the calorimeter. This can lead to an inaccurate measurement of the heat flow between the system being studied and the surroundings, affecting the calculated heat capacity or enthalpy change.


What are thermodynamic processes?

It means that the proces is somewhere between an isothermal and a adiabatic proces You have some heat transfer, but not all of it.


What are the thermodynamic processes?

It means that the proces is somewhere between an isothermal and a adiabatic proces You have some heat transfer, but not all of it.


What is isothermal change definition?

Isothermal changes are those changes which when take place, there is an exchange of energy between the system and surroundings so that temperature of the system doesn't change. Such processes have to be carried out in a conducting vessel.