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An isothermal calorimeter is a tool used to bind small molecules to larger macromolecules, and determine the thermodynamic parameters of interactions in a solution. An isoperibol calorimeter measures the heat created by a sample burned under an oxygen atmosphere in a closed vessel surrounded by water, in controlled conditions. The measurement is known as a BTU value.

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In an isothermal calorimeter, the temperature inside the calorimeter remains constant during the measurement, preventing any heat exchange with the surroundings. In an isoperibol calorimeter, the calorimeter is well-insulated and allows heat exchange with the surroundings, but the heat loss or gain is accurately measured and compensated for.

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11mo ago
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An isoperibolic calorimeter has a constant temperature of the reactor jacket.

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12y ago
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Q: Difference between isothermal and isoperibol calorimeter?
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