In Amateur Radio, PEP stands for Peak Envelope Power. This is the power of the radio wave at the top and bottom of each of it's cycles. For example, if the PEP of a wave is 100 Watts, then at the top of the wave the power is exactly 100 Watts. At the bottom of the wave, things get a little bit weirder, as the power is -100 Watts. I know it's a little hard to wrap your brain around. At the exact middle of the wave, the power is 0 watts.
Peak envelope power (PEP) is the highest envelope power supplied to the antenna transmission line by a
transmitter during any full undistorted RF cycle or series of complete radio frequency cycles.
The United States Federal Communications Commission uses PEP to set maximum power standards for amateur radio transmitters.
PEP is normally considered the occasional or continuously repeating crest of the modulation
envelope under normal operating conditions.
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